Unveiling Synergistic Interface Effects on Charge Trapping Regulation in Polymer Composite Dielectrics through...

Interface design is a promising strategy to enhance the dielectric strength in polymer composites through regulating the charge transport process. However, the targeted exploitation of interface effects is limited due to a lack of fundamental understanding of the underlying mechanisms involving elementary electronic processes and details of the intricate interplay of characteristics of molecular building blocks and the interfacial morphology - details that cannot fully be resolved with experimental methods or commonly used band transport models. Here, we instead build a proper theoretical framework for polymer dielectrics based on charge hopping and employ a multiscale modeling approach linking the quantum properties of the charge carriers with nano- and mesoscale structural details of complex interfaces. Applied to a prototypical application-proven cellulose-oil interface system, this approach demonstrates that charges are trapped in the disordered region. Specifically, it unveils this trapping as a synergistic effect of two transport-regulating interface mechanisms: back-transfer to the oil region is suppressed by energetic factors, while forward-transfer to the crystalline cellulose is suppressed by low electronic coupling. The insight into the molecular origins of interface effects via dual-interface regulation in the framework of charge hopping offers new development paths for developing advanced energy materials with tailored electrical properties.