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Updated: May 15, 2025

Confocal Imaging of Confined Quiescent and Flowing Colloid-polymer Mixtures
Published on: May 20, 2014
Colloidal transport in periodic potentials: the role of modulated-crowding
Ramón Castañeda-Priego1, Erick Sarmiento-Gómez1,2, Yasamin Mohebi Satalsari2
1Departamento de Ingeniería Física, División de Ciencias e Ingenierías, Campus León, Universidad de Guanajuato, Loma del Bosque 103, Lomas del Campestre, 37150 León, Guanajuato, Mexico.
Abstract:
The transport properties of colloids in external potentials are often studied at low concentrations to avoid particle-particle interactions. However, the impact of concentration on colloidal dynamics under external potentials has received limited attention. We examine the effect of concentration on the diffusivity of a quasi-2D colloidal dispersion subjected to a light-induced sinusoidal potential (interference fringes). By measuring particle diffusivity perpendicular to the fringes at various concentrations and laser powers, we find how the particle transport is governed by concentration and the structural organization induced by the external potential. Specifically, we introduce the concept of modulated-crowding for this physical scenario and characterize its influence on the long-time self-diffusion coefficient. These findings are confirmed using Brownian dynamics simulations.
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