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The Quantum-Mechanical Model of an Atom02:45

The Quantum-Mechanical Model of an Atom

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Shortly after de Broglie published his ideas that the electron in a hydrogen atom could be better thought of as being a circular standing wave instead of a particle moving in quantized circular orbits, Erwin Schrödinger extended de Broglie’s work by deriving what is now known as the Schrödinger equation. When Schrödinger applied his equation to hydrogen-like atoms, he was able to reproduce Bohr’s expression for the energy and, thus, the Rydberg formula governing...
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Differential Form of Maxwell's Equations01:17

Differential Form of Maxwell's Equations

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James Clerk Maxwell (1831–1879) was one of the significant contributors to physics in the nineteenth century. He is probably best known for having combined existing knowledge of the laws of electricity and the laws of magnetism with his insights to form a complete overarching electromagnetic theory, represented by Maxwell's equations. The four basic laws of electricity and magnetism were discovered experimentally through the work of physicists such as Oersted, Coulomb, Gauss, and...
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Maxwell-Boltzmann Distribution: Problem Solving01:20

Maxwell-Boltzmann Distribution: Problem Solving

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Individual molecules in a gas move in random directions, but a gas containing numerous molecules has a predictable distribution of molecular speeds, which is known as the Maxwell-Boltzmann distribution, f(v).
This distribution function f(v) is defined by saying that the expected number N (v1,v2) of particles with speeds between v1 and v2 is given by
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Transmission-Line Differential Equations01:26

Transmission-Line Differential Equations

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Transmission lines are essential components of electrical power systems. They are characterized by the distributed nature of resistance (R), inductance (L), and capacitance (C) per unit length. To analyze these lines, differential equations are employed to model the variations in voltage and current along the line.
Line Section Model
A circuit representing a line section of length Δx helps in understanding the transmission line parameters. The voltage V(x) and current i(x) are measured...
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The de Broglie Wavelength02:32

The de Broglie Wavelength

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In the macroscopic world, objects that are large enough to be seen by the naked eye follow the rules of classical physics. A billiard ball moving on a table will behave like a particle; it will continue traveling in a straight line unless it collides with another ball, or it is acted on by some other force, such as friction. The ball has a well-defined position and velocity or well-defined momentum, p = mv, which is defined by mass m and velocity v at any given moment. This is the typical...
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Energy Associated With a Charge Distribution01:21

Energy Associated With a Charge Distribution

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The work done to bring a charge through a distance r is given by the potential difference between the initial and the final position. To assemble a collection of point charges, the total work done can be expressed in terms of the product of each pair of charges divided by their separation distance, defined with respect to a suitable origin. Solving this expression gives the energy stored in a point charge distribution.
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Related Experiment Video

Updated: May 10, 2025

Synthesis of Cyclic Polymers and Characterization of Their Diffusive Motion in the Melt State at the Single Molecule Level
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Synthesis of Cyclic Polymers and Characterization of Their Diffusive Motion in the Melt State at the Single Molecule Level

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Density-Functional Theory for the Dicke Hamiltonian.

Vebjørn H Bakkestuen1, Mihály A Csirik1,2, Andre Laestadius1,2

  • 1Department of Computer Science, Oslo Metropolitan University, Oslo, Norway.

Journal of Statistical Physics
|April 24, 2025
PubMed
Summary
This summary is machine-generated.

This study details density-functional theory for quantum systems, proving a Hohenberg-Kohn theorem and introducing new functionals. Findings reveal low-lying eigenstates as optimizers, enabling an adiabatic-connection formula.

Keywords:
Density-functional theoryDicke modelHohenberg–Kohn theoremMathematical physicsNon-relativistic quantum electrodynamicsRabi modelRepresentability

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Area of Science:

  • Quantum mechanics
  • Condensed matter physics
  • Quantum optics

Background:

  • Density-functional theory (DFT) is a powerful quantum mechanical method.
  • Applying DFT to quantum-electrodynamical (QED) systems presents unique challenges.
  • Existing DFT methods may not fully capture the complexities of QED models.

Purpose of the Study:

  • To develop and analyze density-functional theory for quantum-electrodynamical model systems.
  • To extend the Hohenberg-Kohn theorems to these QED systems.
  • To investigate the properties of constrained-search functionals for pure states and ensembles.

Main Methods:

  • Detailed analysis of density-functional theory.
  • Consideration of the quantum Rabi model, Dicke model, and multi-mode generalizations.
  • Proof of a Hohenberg-Kohn theorem with internal variables (magnetization and displacement).
  • Introduction and analysis of constrained-search functionals for pure states and ensembles.

Main Results:

  • A generalized Hohenberg-Kohn theorem is proven for QED model systems.
  • Magnetization and displacement are identified as internal variables.
  • Optimizers for the pure-state constrained-search functional are found to be low-lying eigenstates.
  • An adiabatic-connection formula is formulated based on these properties.
  • Differentiability of the universal density functional is shown for the Rabi model, implying unique pure-state v-representability.

Conclusions:

  • The study provides a rigorous DFT framework for QED model systems.
  • The findings extend the applicability of DFT to a broader range of quantum phenomena.
  • The developed methods and theorems pave the way for future investigations in quantum many-body physics and quantum optics.