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Direct characterisation of m = ±15/2 ground state in octahedral Dy(III) single-molecule magnets
Vijay S Parmar1, Gemma K Gransbury1, Sophie C Corner1
1Department of Chemistry, School of Natural Sciences, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK. david.mills@manchester.ac.uk.
Abstract:
Two heteroleptic octahedral Dy(III) cis-aryloxide complexes, [Dy(OPh*)2(THF)3X] {HOPh* = 2,6-bis(diphenyl-methyl)-4-tert-butylphenol; X = Cl (1), Br (2)}, have been characterised by multi-frequency electron paramagnetic resonance (EPR) spectroscopy to determine g = 18.9(1) for 1 and 18.3(6) for 2. These are rare examples of Dy(III) single-molecule magnets that have observable EPR spectra.
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