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Updated: May 10, 2025

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Advanced Microporous Framework Membranes for Sustainable Separation.

Xin Liu1, Peiren Liu1, Haochen Wang1

  • 1Smart Hybrid Materials Laboratory (SHMs), Department of Chemistry, Division of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955-6900, Kingdom of Saudi Arabia.

Advanced Materials (Deerfield Beach, Fla.)
|April 25, 2025
PubMed
Summary

Advanced microporous materials like metal-organic frameworks (MOFs) and covalent-organic frameworks (COFs) offer superior separation performance. This review highlights their potential for energy-efficient industrial applications.

Keywords:
covalent organic frameworksmacrocycle and porous organic cagesmetal‐organic frameworksmicroporous membranesselectivityseparation

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Area of Science:

  • Materials Science
  • Chemical Engineering
  • Separation Science

Background:

  • Conventional membranes face limitations in balancing permeability and selectivity.
  • Microporous materials provide tunable pore structures for enhanced separation.

Purpose of the Study:

  • To review recent advancements in four key microporous materials: MOFs, COFs, macrocycles, and POCs.
  • To explore their structure-performance relationships in various separation applications.

Main Methods:

  • Literature review of microporous membrane research.
  • Analysis of structure-property correlations for hydrocarbon, liquid-phase, and ion-selective separations.

Main Results:

  • Microporous membranes demonstrate breakthroughs in hydrocarbon separation, molecular sieving, and ion transport.
  • Tailored pore architectures enable high selectivity and permeability.

Conclusions:

  • Microporous membranes offer a promising route to overcome traditional separation challenges.
  • Further development is needed for scalability, durability, and industrial integration to achieve sustainability goals.