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Production of Pitch from Coal Tar of the Coke Chemical Production "Qarmet"
Aigul T Ordabaeva1, Zainulla M Muldakhmetov1, Mazhit G Meiramov1
1Institute of Organic Synthesis and Chemistry of Coal of Kazakhstan Republic, Alikhanov Str., 1, Karaganda 100012, Kazakhstan.
Abstract:
Medium-temperature pitch was obtained by vacuum distillation of coal tar from the Qarmet coke chemical production. To determine the composition of the organic constituent of the Qarmet coal tar, the component composition was analyzed via gas-liquid chromatography (GLC) methods. The analysis of the component composition of the organic component of coal tar showed that the content of naphthalene and its derivatives is 37.57%, acenaphthene-2.10%, dibenzofurane-3.60%, fluorene-4.63%, phenanthrene-8.63%, anthracene-2.29%, fluoranthene-4.56%, and pyrene-2.84%. It was found that in the obtained pitch sample, indicators such as the content of insoluble in toluene (41.86%), the softening temperature (85-91 °C), and the yield of volatile substances (1.5%) are more consistent with the standards for electrode pitch grade "V". The composition of fractions in baking soda, soluble in toluene and quinoline, has been established. In the fractions of pitch soluble in toluene, 11 components were identified, the main of which re fluoranthene (11.71%), pyrene (10.13%), phenanthrene (7.31%), and benzopyrene (4.84%). Thus, based on the analyses carried out, it was found that the Qarmet resin is suitable for obtaining a V-grade electrode pitch, which can be used in the aluminum industry.
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