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Related Concept Videos

Mortar Properties01:17

Mortar Properties

Mortar properties encompass a range of characteristics crucial for construction and masonry work, including workability, water retention, bond strength, durability, compressive strength, volume change, and appearance. Workability refers to mortar's ability to be easily applied and manipulated without sagging or falling off surfaces, which is important for efficient masonry unit placement and alignment. Water retention is essential to prevent the mortar from losing moisture too quickly to the...
Fineness of Cement01:15

Fineness of Cement

The fineness of cement directly influences the rate of hydration, as the hydration begins at the surface of the cement particles. In addition to hydration, the fineness of cement is vital for various properties of concrete including workability, gypsum requirement, and long-term behavior. The fineness of cement is represented in terms of the specific surface of cement which is typically measured in square meters per kilogram, with several methods available for this determination.
Direct...
Strength of Cement01:20

Strength of Cement

Strength tests for cement are not performed directly on neat cement paste due to difficulty in obtaining consistent, reliable specimens. Instead, cement is typically tested in the form of cement-sand mortar.
For compressive strength tests, ASTM C 109-05 standards prescribe a cement-sand mix ratio of 1:2.75 and a water/cement ratio of 0.485 for making 2-inch cubes. These cubes are mixed, cast, and cured in saturated lime water at 23°C until testing. Flexural strength testing, outlined in ASTM C...
Porosity and Absorption of Aggregate01:20

Porosity and Absorption of Aggregate

Aggregates contain pores of varying sizes; while some are completely enclosed within the particles, others open onto the surface, allowing water to penetrate. The porosity of aggregates is a major factor contributing to the overall porosity of concrete, given that aggregates constitute about three-quarters of concrete's volume.
When all pores in an aggregate are filled with water, the aggregate is considered saturated and surface-dry. If left in dry air, water will evaporate until the aggregate...
Porosity in Cement Paste01:18

Porosity in Cement Paste

The porosity of concrete is a measure of the void spaces within its structure. These spaces impact its strength and durability significantly. When water and cement interact, a chemical reaction called hydration creates a semi-solid paste. This paste includes combined water, making up approximately 23% of the cement's dry mass, and gel water, which fills minuscule voids known as gel pores, accounting for about 28% of the cement gel volume.
The balance of water to cement in the mix is critical—it...
Aggregate Cement Ratio01:21

Aggregate Cement Ratio

The Aggregate Cement ratio refers to the weight of aggregate divided by the weight of cement in a concrete mix. Altering this ratio has profound effects on the concrete's properties. This ratio plays a pivotal role in determining the strength, workability, and durability of concrete. When the Aggregate Cement ratio is higher, the mix is leaner, meaning it has less cement paste to lubricate the aggregate, potentially making the concrete less workable. Such mixes, known as lean, enhance the...

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Cs-Bentonite Clay for Biogas Upgrading: A Numerical Assessment.

Niels Mendel1, Jordanus J P Jordi Boon2, Igor Sîreţanu1

  • 1Physics of Complex Fluids, Faculty of Science and Technology, MESA+ Institute for Nanotechnology, University of Twente, P.O. Box 217, 7500 AE Enschede, The Netherlands.

Industrial & Engineering Chemistry Research
|April 28, 2025
PubMed
Summary
This summary is machine-generated.

This study numerically evaluates Cs-exchanged bentonite clay for biogas upgrading via vacuum-pressure swing adsorption. Cs-bentonite offers high methane recovery and purity at low energy consumption, making it a cost-effective alternative for biogas purification.

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Area of Science:

  • Chemical Engineering
  • Materials Science
  • Environmental Science

Background:

  • Biogas upgrading is crucial for producing biomethane, with vacuum-pressure swing adsorption (VPSA) being a key separation technology.
  • Selective CO2 adsorption over CH4 on sorbent materials is the core principle of VPSA for biogas purification.
  • Cs-exchanged bentonite clay has been previously characterized as a potential sorbent for CO2/CH4 separation.

Purpose of the Study:

  • To numerically assess the performance of Cs-exchanged bentonite clay for biogas upgrading using VPSA.
  • To benchmark the effects of process configurations, ambient temperature, and feed biogas composition on separation efficiency.
  • To determine optimal operating parameters for maximizing productivity and minimizing energy consumption while meeting purity and recovery targets.

Main Methods:

  • Numerical simulation of a VPSA process using Cs-exchanged bentonite clay as the sorbent.
  • Evaluation of seven different process cycle configurations, ranging from single-stage to three-column systems.
  • Analysis of the impact of ambient temperature (15-25 °C) and feed biogas composition (35-45% CO2) on performance metrics.

Main Results:

  • A two-column VPSA unit achieved a methane (CH4) purity of 0.906 and a recovery of 0.967 with a specific energy consumption of 0.072 kWh/Nm3 CH4.
  • Optimal performance was demonstrated for upgrading biogas with 45% CO2 at ambient feed pressure.
  • Increased column numbers and pressure equalization steps further improved CH4 recovery, while favorable CO2 adsorption isotherms contributed to low energy use.

Conclusions:

  • Cs-exchanged bentonite clay is a highly effective and cost-efficient sorbent for biogas upgrading via VPSA.
  • Its high CO2/CH4 selectivity and favorable adsorption characteristics result in high methane recovery and low specific energy consumption.
  • Cs-bentonite presents a compelling alternative to conventional sorbent materials for industrial biogas purification applications.