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Related Concept Videos

Photoluminescence: Applications01:14

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Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...
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Single-component white-light-emitting materials based on lanthanide coordination assemblies.

M L P Reddy1, K S Bejoymohandas2

  • 1CSIR-National Institute for Interdisciplinary Science & Technology (CSIR-NIIST), Thiruvananthapuram, 695 019, India. mlpreddy55@gmail.com.

Dalton Transactions (Cambridge, England : 2003)
|April 29, 2025
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Summary
This summary is machine-generated.

Single-component lanthanide coordination assemblies offer efficient white light-emitting materials (WLEMs) for advanced thin-film devices. These materials enable tunable photoluminescence for next-generation lighting solutions.

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Area of Science:

  • Materials Science
  • Photochemistry
  • Nanotechnology

Background:

  • White light-emitting materials (WLEMs) offer advantages over traditional lighting, including energy efficiency and suitability for thin-film fabrication.
  • Single-component emitters based on lanthanide coordination assemblies are desirable for thinner, easily controlled devices but remain rare.
  • Lanthanide coordination assemblies are gaining attention for their photoluminescent properties, enabling advancements in WLEMs.

Purpose of the Study:

  • To review recent progress in single-component lanthanide coordination assemblies for white light emission.
  • To emphasize the photoluminescent color-tuning properties of these materials.
  • To explore the origin, generation, and manipulation of photoluminescence in these assemblies.

Main Methods:

  • Review of scientific literature on lanthanide coordination assemblies.
  • Analysis of photoluminescence mechanisms, including ligand-centered fluorescence and metal-centered emissions.
  • Focus on specific lanthanide ions such as samarium (Sm³⁺), europium (Eu³⁺), and dysprosium (Dy³⁺).

Main Results:

  • Single-component lanthanide coordination assemblies demonstrate potential as efficient WLEMs.
  • Photoluminescent color tuning is achievable through manipulation of ligand and metal-centered emissions.
  • Ligand-centered fluorescence in the blue range and metal-centered emissions in the visible region contribute to white light generation.

Conclusions:

  • Single-component lanthanide coordination assemblies represent a promising pathway for developing advanced WLEMs.
  • Further research into controlling photoluminescence is crucial for optimizing device performance.
  • These materials offer a viable alternative for next-generation lighting and display technologies.