Double-Walled Mesoporous Hydrogen-Bonded Organic Frameworks with High Methane Storage Capacity
Ruihua Zhang1,2, Chun Tang1,2, Shuliang Yang2,3
1Department of Chemistry, The University of Hong Kong, Hong Kong SAR 999077, China.
Abstract:
The development of mesoporous hydrogen-bonded organic frameworks (HOFs) is critically important for various applications, yet it poses significant challenges. Herein, we present the synthesis and characterization of a robust mesoporous HOF, RP-H200, constructed through the orchestration of π-π stacking and hydrogen bonding interactions in a 2-fold interpenetrated framework. RP-H200 features a unique double-walled structure with a pore size of 3.6 nm, representing the largest pore size among reported HOFs to date. The framework exhibits a high surface area of 2313 m2 g-1, with aromatic surfaces dominating the mesoporous channels. The methane storage performance of RP-H200 reaches a high capacity of 0.31 g g-1 at 270 K/100 bar and 0.25 g g-1 at 296 K/100 bar. The combination of large permanent mesoporosity, excellent thermal stability, and high surface area in RP-H200 makes it a promising candidate for clean energy storage and other functions.
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