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Improved CO2 conversion to methanol promoted by ionic liquid additives using a Cu/ZnO/Al2O3 heterogeneous catalyst
Zohaib Suhail1, Christopher J Koch1, Alain Goeppert1
1Loker Hydrocarbon Research Institute and Department of Chemistry, Chemical Engineering and Materals Science, University of Southern California, 837 Bloom Walk, Los Angeles, CA 90089-1661, USA. gprakash@usc.edu.
Abstract:
An efficient amine-based CO2 hydrogenation to methanol system using a Cu/ZnO/Al2O3 heterogeous catalyst was promoted by ionic liquid additives. Relative to a system without an ionic liquid, methanol yields greatly improved when an imidazolium-based ionic liquid [BMIm][OAc] was added. Among the amines tested, triethanolamine yielded the highest conversions.
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