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Updated: May 9, 2025

08:43
A Fluorescence Fluctuation Spectroscopy Assay of Protein-Protein Interactions at Cell-Cell Contacts
Published on: December 1, 2018
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Confinement-supported aurophilic interaction
Youssoupha Diack1, Sonia Mallet-Ladeira2, Denis Lesage3
1CNRS/Université de Toulouse, Laboratoire Hétérochimie Fondamentale et Appliquée (UMR 5069), 118 Route de Narbonne, 31062, Toulouse cedex 9, France. didier.bourissou@univ-tlse3.fr.
Abstract:
An anionic cyclotricatechylene cage (H) is shown (NMR, mass spectrometry and X-ray diffraction) to encapsulate cationic Au(I) complexes. As a result, an unprecedented bimetallic Au(I) complex (GG@H) has been characterized, in which confinement supports aurophilic interaction, even without bridging ligands.
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