Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Valence Bond Theory02:45

Valence Bond Theory

31.1K
Overview of Valence Bond Theory
31.1K
Carbocations02:10

Carbocations

10.7K
Carbocations are one of the reaction intermediates formed during several nucleophilic substitutions or elimination reactions. A carbocation is an electron-deficient species with the central carbon atom having six electrons and three bonded atoms. The central carbon in a carbocation is sp2 hybridized with trigonal planar geometry. It has an empty p orbital perpendicular to the plane of the structure that can accept electrons. Thus, carbocations act as strong electrophiles and may react with any...
10.7K
Covalent Bonding and Lewis Structures02:46

Covalent Bonding and Lewis Structures

46.8K
Compared to ionic bonds, which results from the transfer of electrons between metallic and nonmetallic atoms, covalent bonds result from the mutual attraction of atoms for a “shared” pair of electrons. 
46.8K
Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide02:44

Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide

9.6K
Alkenes are converted to 1,2-diols or glycols through a process called dihydroxylation. It involves the addition of two hydroxyl groups across the double bond with two different stereochemical approaches, namely anti and syn. Dihydroxylation using osmium tetroxide progresses with syn stereochemistry.
9.6K
Oxidative Cleavage of Alkenes: Ozonolysis01:46

Oxidative Cleavage of Alkenes: Ozonolysis

9.7K
In ozonolysis, ozone is used to cleave a carbon–carbon double bond to form aldehydes and ketones, or carboxylic acids, depending on the work-up.
Ozone is a symmetrical bent molecule stabilized by a resonance structure.
9.7K
Lewis Structures of Molecular Compounds and Polyatomic Ions02:54

Lewis Structures of Molecular Compounds and Polyatomic Ions

34.2K
To draw Lewis structures for complicated molecules and molecular ions, it is helpful to follow a step-by-step procedure as outlined:
34.2K
  1. Home
  3. Research Domains
  5. Physical Sciences
  7. Condensed Matter Physics
  9. Surface Properties Of Condensed Matter
  11. Core-valence Double Ionization Of Carbon Suboxide

Core-valence double ionization of carbon suboxide

Emelie Olsson1, Lucas M Cornetta2, Veronica Daver Ideböhn1

  • 1Department of Physics, University of Gothenburg, Origovägen 6B, 412 58, Gothenburg, Sweden.

Scientific Reports
|May 6, 2025

Related Experiment Videos

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
07:36

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy

Published on: November 9, 2019

7.9K
Achieving Moderate Pressures in Sealed Vessels Using Dry Ice As a Solid CO2 Source
06:26

Achieving Moderate Pressures in Sealed Vessels Using Dry Ice As a Solid CO2 Source

Published on: August 17, 2018

9.9K
Characterizing Lewis Pairs Using Titration Coupled with In Situ Infrared Spectroscopy
07:49

Characterizing Lewis Pairs Using Titration Coupled with In Situ Infrared Spectroscopy

Published on: February 20, 2020

9.0K

View abstract on PubMed

Summary
This summary is machine-generated.

We measured core-valence double ionization spectra of carbon suboxide, finding significant differences from single ionization spectra. Advanced calculations including orbital overlap improved agreement, aiding spectral feature assignments and Auger decay analysis.

Area of Science:

  • Atomic and Molecular Physics
  • Quantum Chemistry
  • Spectroscopy

Background:

  • Core-valence double ionization is a complex process involving simultaneous removal of electrons from core and valence shells.
  • Understanding these processes is crucial for interpreting complex molecular spectra and electronic structure.
  • Carbon suboxide (C2O2) presents a unique system for studying core-level electron dynamics due to its distinct carbon environments.

Purpose of the Study:

  • To measure and analyze the core-valence double ionization spectra of carbon suboxide.
  • To compare experimental spectra with theoretical calculations to understand the ionization dynamics.
  • To assign spectral features and investigate Auger decay mechanisms following core ionization.

Main Methods:

  • Experimental measurement of core-valence double ionization spectra using synchrotron radiation above the O 1s and C 1s edges.

Related Experiment Videos

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
07:36

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy

Published on: November 9, 2019

7.9K
Achieving Moderate Pressures in Sealed Vessels Using Dry Ice As a Solid CO2 Source
06:26

Achieving Moderate Pressures in Sealed Vessels Using Dry Ice As a Solid CO2 Source

Published on: August 17, 2018

9.9K
Characterizing Lewis Pairs Using Titration Coupled with In Situ Infrared Spectroscopy
07:49

Characterizing Lewis Pairs Using Titration Coupled with In Situ Infrared Spectroscopy

Published on: February 20, 2020

9.0K
  • Comparison of experimental spectra with theoretical electronic structure calculations using the sudden approximation.
  • Analysis of Auger decay spectra following core hole formation at different carbon atoms.

    • Main Results:

    • Core-valence double ionization spectra of carbon suboxide show significant deviations from single ionization spectra.
    • Theoretical calculations incorporating core-valence orbital overlap improve agreement with experimental data.
    • Auger decay following C 1s ionization exhibits selectivity in final multiply charged states, dependent on the initial ionization site.

    Conclusions:

    • A more complex theoretical description, including orbital overlap, is necessary for accurate modeling of core-valence double ionization in carbon suboxide.
    • Spectral features can be assigned by comparing experimental and calculated spectra.
    • Auger decay pathways are sensitive to the initial core ionization site, providing insights into molecular electronic structure.