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Luminescence Lifetime-Based Sensing of Water Turbidity
Ya Jie Knöbl1, Iman Nakhli1, María Del Mar Darder1
1Chemical Optosensors & Applied Photochemistry Group (GSOLFA), Dpmt. of Organic Chemistry, Faculty of Chemistry, Complutense University of Madrid, Madrid 28040, Spain.
A new luminescence-based sensor offers accurate water turbidity measurements. This cost-effective device uses dual-lifetime referencing for precise detection across various ranges, overcoming limitations of commercial sensors.
Area of Science:
- Analytical Chemistry
- Environmental Science
- Sensor Technology
Background:
- Commercial turbidity sensors are often expensive, bulky, and fragile.
- Accurate turbidity measurement is crucial for water quality assessment.
- Research is ongoing to develop alternative, more robust sensing methods.
Purpose of the Study:
- To develop and characterize a novel luminescence-based sensor for water turbidity.
- To utilize a dual-lifetime reference scheme for enhanced measurement accuracy.
- To provide a cost-effective and potentially more robust alternative to existing sensors.
Main Methods:
- A dual-lifetime luminescence referencing scheme was employed.
- A reference fluorophore (BCT in PVC) and an indicator luminophore (RD3 in PCA) were used.
- The sensor measures the luminescence phase shift caused by turbidity as water flows between dye layers.
Main Results:
- The sensor accurately detects turbidity in ranges of 0-1000 NTU, 0-500 NTU, and 0-300 NTU for different optical pathlengths (1-2 cm).
- Achieved accuracy is 1 NTU (0.3 NTU between 0-10 NTU).
- The sensor demonstrated instantaneous, temperature-independent response, free from dissolved oxygen and chlorophyll interference, and performed well over 11 days in real-world conditions.
Conclusions:
- The developed luminescence sensor provides a viable, accurate, and potentially more robust method for water turbidity monitoring.
- The dual-lifetime referencing scheme effectively translates turbidity into measurable luminescence phase shifts.
- The sensor's performance in real-world conditions indicates its practical applicability for water quality assessment.
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