Amphiphilic Styrene-Based Pyrene Derivatives: Tunable Aggregation Luminescence and Their Photo-Induced Dimerization...

Since the discovery of the aggregation-induced emission (AIE) phenomenon, various stimuli-responsive materials have been rapidly developed. However, how to achieve the transition between aggregation-caused quenching (ACQ) and AIE through molecular design is an urgent problem to be solved. In this work, we synthesized and studied the aggregation luminescence behavior and photochromism of two different substituted pyrene ethylene derivatives, 1-H and 1-CN. Due to the different substituents attached to the ethylene unit, 1-H exhibits ACQ luminescence behavior. When the substituent is a cyanide group, it exhibits AIE behavior. In addition, the ordered nanoparticles formed by self-assembly in aqueous solution exhibit interesting photo-induced cyclization behavior, which leads to fluorescence quenching under ultraviolet light irradiation (λ = 365 nm). Therefore, due to their amphiphilicity and photo-responsiveness, these compounds can be used as anticounterfeiting inks in information encryption. This work contributes new members to the family of amphiphilic photo-responsive materials and demonstrates their potential applications in optical information storage and multi-color luminescence.