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Toxicological risk assessment and sources of heavy metal(loid)s using compositional data analysis, Astore River
Wajid Ali1, Said Muhammad1, Cem Tokatli2
1National Centre of Excellence in Geology, University of Peshawar, 25130 Peshawar, Pakistan.
Abstract:
Himalayan rivers were observed to be more vulnerable having irregular water flows, flooding, and contamination due to various stresses, including climate change, urbanization, and industrial development. This study investigated the occurrence, sources, ecological, and health-based ramifications for heavy metal(loid)s (HM), i.e., As, Cu, Zn, Co, Pb, Sb, Cr, Cd, Mn, and Ni in the Astore river basin (ARB), Himalayas, Pakistan. Results of HM contamination index (HCI) estimations suggested that 2.43 %, 12.2 %, and 24.4 % of water samples from the Astore and Rupal valleys may pose strong, moderate, and low toxicity risks, respectively. Pb, Cu, and Cd contribute more to the aquatic toxicity than any other HM included in the ecological risk index (ERI) estimations. Children are the most vulnerable age group to health ailments caused by HM. Statistical analyses revealed that geogenic sources mainly contribute to HM, except for Ni and Cr, which are mainly derived from anthropic sources in ARB.
