Advances in chiral luminescent liquid crystals (CLLCs): from molecular design to applications

Research on circularly polarized luminescent (CPL) materials has evolved into a hot research topic because of their potential application prospects in the optoelectronics and chiroptical fields. Achieving a high g_lum value and high quantum efficiency is essential and challenging in CPL research. To date, various material design strategies, such as chiral organic small molecules, CPL polymers, chiral lanthanide complexes, chiral liquid crystals and supramolecular self-assembly, have been proposed to achieve a CPL emitter with a high g_lum value. Among them, chiral luminescent liquid crystals (CLLCs) are recognized as a key approach for achieving CPL materials with a high g_lum factor owing to their exceptional optical properties and flexibility. In this review, we focused on the various synthesis methods employed for developing CLLCs, their properties and their potential applications. The synthesis section discusses various approaches employed to design chiral luminescent liquid crystals, including (i) doping systems for incorporating chiral dopants into achiral liquid crystalline hosts and (ii) nondoping methods for preparing AIE active chiral luminescent liquid crystalline materials. The section on properties highlights how chirality influences the optical, electronic and structural characteristics of CLLCs. Finally, we discuss the diverse applications of CLLCs from photonics and chiral switching to optoelectronic devices and beyond. This review provides new insights into recent research developments and future opportunities in this booming research field. We anticipate that this review could offer a clear picture of the interesting properties of chiral luminescent liquid crystal materials and inspire more researchers to work in this potential area.