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Understanding the mechanism behind improved cycling stability of FeF3 cathode in lithium
Yuta Maeyoshi1, Noboru Taguchi1, Kazuki Yoshii1
1Research Institute of Electrochemical Energy, Department of Energy and Environment, National Institute of Advanced Industrial Science and Technology (AIST), 1-8-31 Midorigaoka, Ikeda, Osaka 563-8577, Japan. y.maeyoshi@aist.go.jp.
Abstract:
We investigate the mechanism behind the improved discharge/charge cycling stability of FeF3 cathode in lithium bis(fluorosulfonyl)amide (LiFSA)-concentrated electrolytes. Macroscopic and microscopic analyses reveal that the concentrated electrolyte effectively suppresses the formation of inactive Fe and LiF in the cycled FeF3 at the charged state, thus improving the cycling stability.
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