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Electrically Induced Topological Chirality Switching in Orbital-Engineered Covalent Organic Radical Framework
Yifan Li1, Kai Zhang2, Yu Pan3
1Hefei National Laboratory, University of Science and Technology of China, Hefei, Anhui 230088, China.
Researchers developed bipolar topological magnetic semiconductors using 2D covalent organic radical frameworks for tunable quantum anomalous Hall effects. This enables electrically driven chiral switching in spintronics and quantum devices.
Area of Science:
- Materials Science
- Condensed Matter Physics
- Organic Chemistry
Background:
- Quantum anomalous Hall (QAH) insulators are key for spintronics and quantum devices.
- Current methods using magnetic fields are not scalable or energy-efficient.
Purpose of the Study:
- To engineer topological properties for advanced spintronics.
- To realize electrically driven chiral switching of the QAH phase.
Main Methods:
- Utilized orbital engineering in two-dimensional covalent organic radical frameworks (2D CORFs).
- Synthesized bipolar topological magnetic semiconductors (BTMS).
- Employed carrier doping and heteroatom substitution (N/B) for tuning.
Main Results:
- Achieved robust room-temperature ferromagnetism (TC ≈ 508 K).
- Demonstrated spin-polarized Dirac cones and flat bands with opposite Chern numbers.
- Confirmed chirality inversion of edge currents via Berry curvature analysis.
Conclusions:
- 2D CORFs provide a versatile platform for electrically tunable topological quantum devices.
- This work bridges organic chemistry and chiral spintronics.
- Enables scalable and energy-efficient QAH devices.
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