Reuse of spent granular activated carbon for PFAS removal following hydrothermal alkaline treatment

Per- and polyfluoroalkyl substances (PFAS) pose a significant challenge for water treatment facilities facing strict regulatory standards. Granular activated carbon (GAC) adsorption is effective for PFAS removal, but media exhaustion and replacement can be costly, highlighting the need for innovative GAC regeneration methods. While thermal reactivation of GAC can eliminate adsorbed PFAS, it requires high temperatures and is mainly feasible for large-scale media users. This study investigates spent GAC regeneration by hydrothermal alkaline treatment (HALT), which applies subcritical water (e.g., 350 °C, 16.5 MPa) amended with strong base (e.g., NaOH) to destroy PFAS. Previous research indicates that HALT successfully degraded and defluorinated PFAS while maintaining GAC surface area and equilibrium adsorption capacity. This study presents data from rapid small-scale column tests (RSSCTs) demonstrating effective removal of long-chain PFAS by a HALT-treated spent GAC sample collected from a long-term PFAS treatment field pilot study (BV₅₀ > 50,000 for PFOS, PFHxS, and PFNA). HALT-treated virgin GAC and untreated virgin GAC evaluated using RSSCTs exhibited similar PFAS breakthrough behavior, with comparable overall PFAS removal to the HALT-treated spent GAC. Physisorption measurements revealed that HALT recovers GAC pore surface area lost during field-use. Surface chemical characterization techniques indicated mostly similar surface composition and functional groups in virgin and HALT-treated GAC, with limited change in the carbon structure following HALT and differences between virgin and field-spent samples. Analyses of reactor liquid products, media mass loss, and NaOH neutralization by GAC also provided evidence for removal of adsorbed non-target organic matter and possible GAC surface renewal by carbon gasification reactions occurring in parallel with PFAS destruction, analogous to surface carbon burn-off that occurs during high-temperature thermal reactivation. Retention of adsorbed metal ions that accumulated on the spent GAC during field testing may be responsible for enhanced adsorption behavior observed for some PFAS following HALT regeneration. Results indicate that HALT can enable reuse of spent GAC, potentially alleviating the high demand for virgin media in PFAS treatment processes.