Related Experiment Video
Updated: May 22, 2025

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Laboratory-determined Phosphorus Flux from Lake Sediments as a Measure of Internal Phosphorus Loading
Published on: March 6, 2014
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Quantifying Summer Internal Phosphorus Loading in Large Lakes across the United States
Smitom S Borah1, Natalie G Nelson2, Owen W Duckworth3
1Department of Civil, Construction, and Environmental Engineering, North Carolina State University, Raleigh, North Carolina 27606, United States.
Environmental Science & Technology
|May 20, 2025
Summary
Internal phosphorus loading (IPL) significantly impacts freshwater quality. Our study models phosphorus release from sediments in 5899 US lakes, revealing high rates in agricultural areas and identifying critical management needs.
Area of Science:
- Environmental Science
- Limnology
- Water Quality Management
Background:
- Internal phosphorus loading (IPL) is a major phosphorus source in freshwater systems, delaying water quality improvements.
- Estimating IPL is challenging due to measurement and modeling difficulties, leaving many systems unassessed.
- Phosphorus (P) is a key nutrient driving eutrophication in aquatic ecosystems.
Purpose of the Study:
- To develop a modeling framework for estimating summer anoxic sediment release rates (SRRs) of phosphorus.
- To assess IPL across 5899 large lakes and reservoirs in the contiguous US (CONUS).
- To identify regions where IPL is a critical factor for nutrient management.
Main Methods:
- Developed a framework combining random forest models for bottom-water temperature and total phosphorus (TP) with a mixed-effects regression model for SRR.
- Incorporated uncertainty propagation across all model components.
- Analyzed data from 5899 lakes and reservoirs (surface area > 1.0 km², mixing depth < maximum depth) across the CONUS.
Main Results:
- Mean summer SRR ranged from 1 to 37 mg/m²/day across CONUS lakes.
- 31% of waterbodies exhibited SRR > 10 mg/m²/day, often linked to high predicted surface-water TP, especially in agricultural regions.
- In dry summers, IPL exceeded external loading in 26% of watersheds.
Conclusions:
- The developed framework provides crucial estimates for IPL, addressing a significant data gap.
- High SRR is prevalent in agricultural areas, highlighting the need for targeted watershed management.
- IPL can be a dominant phosphorus source, necessitating its consideration in water quality improvement strategies.

