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Updated: May 9, 2026

Sediment Core Extrusion Method at Millimeter Resolution Using a Calibrated, Threaded-rod
Published on: August 17, 2016
Individual Microfossil δ13C Shows That δ13Corg Excursions in the Neoproterozoic Chuar Group Do Not Reflect the
Heda Agić1,2, Susannah M Porter1, Phoebe A Cohen3
1Department of Earth Science, University of California Santa Barbara, Santa Barbara, California, USA.
Abstract:
Changes in δ13C value of bulk sedimentary organic matter (OM) throughout Earth's history are thought to reflect carbon cycle perturbations, but as sedimentary OM may derive from multiple sources, it could also record other processes. We measured δ13C of microscale components of shale OM using nano-EA-IRMS to investigate drivers of large-magnitude carbon isotope excursions (CIE) in the late Tonian Chuar Group, USA. Components included organic-walled microfossils, kerogen, graphite, and macerate size-fractions. Microfossils δ13C has a broad range within samples, but average values vary little throughout stratigraphy and are decoupled from bulk δ13Corg, showing that these positive CIEs are not driven by secular changes in the carbon cycle. Instead, our fine-scale approach identified enriched components that can account for the CIE: exogenous clasts of kerogen and graphite, a finer macerate fraction, and abundant Eosynechococcus-a bloom-forming phytoplankter. The presence of these 13C-enriched particles indicates that the positive CIE signals were driven by a combination of allochthonous input/enhanced productivity, as well as thermal alteration. Fine-scale measurements can tease apart contributors to bulk δ13Corg records and offer insights into the Proterozoic carbon cycle.
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