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Organometallic compounds are compounds that contain a carbon–metal bond. Carbon belongs to an organyl group like alkyl, aryl, allyl, or benzyl groups. The metal can be from Group I or Group II of the periodic table, a transition metal, or a semimetal.

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Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks

Synthesis of Single-Crystalline Core-Shell Metal-Organic Frameworks

Published on: February 10, 2023

A new carborane scaffold for assembling metal-organic frameworks.

Hunter J Windsor¹, Thomas J C Carraro¹, Robert J Walwyn¹

¹School of Chemistry, Faculty of Science, The University of Sydney, Camperdown, New South Wales 2006, Australia. hunter.windsor@sydney.edu.au.

Chemical Communications (Cambridge, England)

|June 4, 2025

Summary

This summary is machine-generated.

Researchers developed a new metal-organic framework (MOF) using a carborane ligand, significantly improving its thermal stability. This advancement expands possibilities for creating advanced carborane-based materials.

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Synthesis and Characterization of Functionalized Metal-organic Frameworks

Synthesis and Characterization of Functionalized Metal-organic Frameworks

Published on: September 5, 2014

Area of Science:

Materials Science
Inorganic Chemistry
Nanotechnology

Background:

Metal-organic frameworks (MOFs) are porous materials with diverse applications.
Thermal stability is a critical property for MOF performance in various environments.
Carboranes are unique boron-containing clusters with potential for material modification.

Purpose of the Study:

To synthesize a novel di-4-pyridyl closo-1,12-carborane ligand.
To incorporate this ligand into a zinc(II)-based metal-organic framework (MOF).
To investigate the impact of carborane incorporation on the MOF's thermal stability.

Main Methods:

Synthesis of the di-4-pyridyl closo-1,12-carborane ligand.
Crystallization of the zinc(II)-based MOF with the carborane ligand.
Thermal gravimetric analysis (TGA) to assess thermal stability.

Main Results:

The synthesized carborane ligand was successfully incorporated into the Zn(II)-MOF structure.
The resulting carborane-modified MOF demonstrated enhanced thermal stability compared to the unmodified MOF.
The synthetic strategy is adaptable to various linker geometries and symmetries.

Conclusions:

Incorporation of the di-4-pyridyl closo-1,12-carborane ligand significantly enhances the thermal stability of the Zn(II)-MOF.
The developed synthetic approach offers a versatile method for creating carborane-derived polymeric assemblies.
This work expands the ligand pool for designing advanced functional materials with improved properties.