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Published on: August 20, 2018
Assembling 4f and 3d-4f clusters as single-molecule magnets by automatic fixation of atmospheric CO2
Cai-Ming Liu1,2
1Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory for Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China. cmliu@iccas.ac.cn.
None:
Emerging methods for cluster assembly through fixation of CO2 in air provide an innovative approach for the development of novel single-molecule magnets (SMMs). Both 4f cluster SMMs and 3d-4f cluster SMMs may be assembled using this green pathway. Even after the introduction of chirality and/or intermolecular hydrogen bonds, such SMMs can be further made into multifunctional molecular materials at the nanoscale. In this paper, 4f cluster SMMs and 3d-4f cluster SMMs assembled by the fixation of CO2 in air are briefly reviewed, and an outlook of the promising future prospects in this field is provided.
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