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Trends in Lattice Energy: Ion Size and Charge02:54

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An ionic compound is stable because of the electrostatic attraction between its positive and negative ions. The lattice energy of a compound is a measure of the strength of this attraction. The lattice energy (ΔHlattice) of an ionic compound is defined as the energy required to separate one mole of the solid into its component gaseous ions. For the ionic solid sodium chloride, the lattice energy is the enthalpy change of the process:
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Study of LiCoO2+C60 hybrid cathode using neutron and ion-beam profiling methods.

G Ceccio1, J Vacik1, V Lavrentiev1

  • 1Department of Neutron and Ion Methods, Nuclear Physics Institute (NPI) of the Czech Academy of Sciences (CAS), Řež 130, 250 68, Czech Republic.

Applied Radiation and Isotopes : Including Data, Instrumentation and Methods for Use in Agriculture, Industry and Medicine
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Hybrid cathodes for all-solid-state Li-ion batteries (ASSLIBs) using LiCoO2 and C60 were developed. Neutron Depth Profiling and Rutherford Back Scattering revealed element distribution influenced by C60 and current collectors.

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All-solid-state Li-Ion batteryIon beam sputteringNeutron depth profilingRutherford backscattering

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Solid-State Physics

Background:

  • All-solid-state Li-ion batteries (ASSLIBs) require advanced cathode materials for improved safety and energy density.
  • Hybrid cathode structures offer potential for enhanced electrochemical performance.
  • Understanding element distribution is crucial for optimizing ASSLIB performance.

Purpose of the Study:

  • To prepare and characterize thin films of a hybrid LiCoO2 (LCO) + C60 cathode for ASSLIBs.
  • To investigate the depth distribution of constituent elements (Li, Co, C, O) within the hybrid film.
  • To determine the influence of the C60 phase and current collector on element distribution.

Main Methods:

  • Simultaneous ion beam sputtering of LCO and thermal evaporation of C60 to create hybrid thin films.
  • Neutron Depth Profiling (NDP) for precise elemental depth profiling.
  • Rutherford Backscattering (RBS) for complementary elemental analysis.

Main Results:

  • NDP and RBS confirmed element depth distributions in the sub-micrometer LCO+C60 films.
  • The presence of C60 increased Li accumulation on the surface and decreased it slightly below.
  • Uneven distributions of Co, C, and O were observed, influenced by C60 and the current collector.

Conclusions:

  • The C60 phase significantly impacts Li distribution in hybrid LCO+C60 cathodes.
  • Element redistribution occurs at the surface after current collector deposition.
  • Electrochemical potential differences are likely responsible for the observed uneven element distributions.