Unveiling the Key Role of Surface Oxidation through Quantifying Reaction Kinetics in Heterogeneous Catalysis for...

Quantifying surface-specific kinetics of organic oxidation in heterogeneous catalytic systems remains a critical challenge due to the interplay of adsorption and complex reaction mechanisms. In this study, we introduce a novel kinetic framework that distinguishes surface reaction kinetics (k_c) from conventional solution-phase kinetics (k_b), using nitrogen-doped porous carbon (NPC) as a model catalyst with high adsorption capacity and exceptional efficacy in peroxymonosulfate (PMS) activation. By directly analyzing the selective oxidation of fully adsorbed para-substituted phenolic compounds (p-PCs), we precisely quantified k_c and established robust QSAR models with remarkable linear correlations (R² = 0.862-0.912) to molecular descriptors such as Hammett constant (σ), highest occupied molecular orbital energy (E_HOMO), and ionization potential (IP). In contrast, k_b-based models showed weaker correlations (R² = 0.363-0.551), reflecting interference from adsorption-desorption dynamics. This distinction underscores the limitations of solution-phase kinetics in systems with strong adsorption properties and highlights the enhanced mechanistic understanding and predictive power of surface-specific models. Further analysis revealed surface-selective oxidation via an electron transfer pathway, predominantly governed by the electronic properties of p-PCs rather than their adsorption affinity. These findings provide a valuable approach to accurately capture surface reactivity and predicting pollutant behavior in heterogeneous sorption-oxidation systems.