Carbon-Halloysite Nanocomposites and Their Adsorption Characteristics for Pharmaceuticals-A Naproxen Case Study

The synthesis of carbon-halloysite nanocomposites was carried out using aqueous sucrose solutions as a carbon precursor. Raw and calcined halloysite with different grain size classes were used as a carbon support. The influence of halloysite grain size and the calcination process on the carbon concentration in the composites and their adsorption characteristics towards the separation of naproxen from aqueous solutions was identified experimentally. The kinetic conditions of the process (pseudo-second-order kinetic model) indicate a favorable increase in the number of active sites formed after the deposition of the carbon layer on the surface of halloysite particles. Validation of the Langmuir multi-center isotherm adsorption model indicates a separation mechanism associated with the occurrence of multiple active centers on the nanocomposite adsorbent surface and the effect of separation without dissociation of naproxen particles. The obtained carbon-halloysite nanocomposite, due to the relatively cheap and simple, environmentally friendly production methodology and the required inexpensive raw materials, can be widely used in effective and common, economical treatment of wastewater streams from naproxen. The observed naproxen separation process effects are significant.