Green Fabrication of Phosphorus-Containing Chitosan Derivatives via One-Step Protonation for Multifunctional...

With the increasing urgency of petroleum resource scarcity and environmental challenges, the development of degradable bio-based flame retardants has become crucial for enhancing the fire safety of organic materials. In this work, a phosphorus-containing chitosan derivative (CS-PPOA) was synthesized via a one-step protonation reaction between chitosan (CS) and phenylphosphinic acid (PPOA) under mild conditions. The resulting multifunctional flame-retardant coating was applied to polyester (PET) fabrics. Comprehensive characterization using FT-IR, XPS, and NMR confirmed the successful protonation of chitosan amino groups through electrostatic interactions, forming a stable ionic complex. The CS-PPOA solution exhibited excellent rheological properties and film-forming ability, producing films with over 80% optical transmittance and flexibility. Thermogravimetric analysis (TGA) revealed that CS-PPOA achieved char residue yields of 76.8% and 40.2% under nitrogen and air atmospheres, respectively, significantly surpassing those of acetic acid-protonated chitosan (CS-HAc). The limiting oxygen index (LOI) of CS-PPOA increased to 48.3%, and vertical burning tests demonstrated rapid self-extinguishing behavior. When applied to PET fabrics at a 15% loading, the LOI value improved from 20.3% (untreated fabric) to 27.8%, forming a dense char layer during combustion while completely suppressing melt dripping. Additionally, the coated fabric exhibited broad-spectrum antibacterial activity, achieving a 99.99% inhibition rate against Escherichia coli and Staphylococcus aureus. This study provides a novel strategy for the green and efficient preparation of multifunctional bio-based flame-retardant coatings.