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Magnetic Biochar Derived from Waste Bamboo as a Peroxymonosulfate Activator for Tetracycline Hydrochloride
Xingyan Huang1,2,3,4, Yuanlong Chen1,2,3,4, Yujia Zhang2,3,4
1College of Forestry, Sichuan Agricultural University, Chengdu 611130, China.
Abstract:
Magnetic Fe and N-doped biochar (FeN-BC) was synthesized from waste bamboo through microwave pyrolysis and used as a catalyst for the degradation of tetracycline hydrochloride (TC) with peroxymonosulfate (PMS). The results showed that doping with Fe improved the recovery performance of biochar and the N-doping enhanced the activity of PMS. Simultaneously, it achieved a high degradation efficiency for TC (93%) under optimized conditions within 30 min. Electron paramagnetic resonance (EPR) and quenching experiments indicated that the main active radicals present in the experiment were SO4•- and •OH. Additionally, FeN-BC demonstrated good catalytic performance in the TC degradation process in a real water environment after five cycles. This work presents a practical strategy for preparing magnetic biochar to degrade organic pollutants from wastewater.

