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From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
Published on: March 24, 2018
Pillar[5]arene-based ionic single crystals formed by dual self-assemblies through host-guest and ionic interactions
Ting Zhang1,2, Lulu Wang2, Hui Li1
1CAS Key Laboratory of Chemistry of Northwestern Plant Resources and Key Laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China. jiachen@licp.cas.cn.
Abstract:
This study reports the first preparation of an ionically crosslinked pillar[5]arene single-crystal material (DMIBP5-NA) featuring a unique dual self-assembly structure. The material demonstrates excellent adsorption performance toward iodine vapor with an equilibrium adsorption capacity reaching 3.28 g g-1.
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