Reactivated Cathode Material from Waste Alkaline Batteries for Supercapacitor Electrodes: Interplay Study Between...

Waste alkaline batteries (WABs) are rapidly consumed over billions of tons annually, which presents significant challenges for both the environment and public health. To tackle these challenges, recycling WABs through sustainable methods can effectively align with the principles of a circular economy. It not only addresses pressing waste management issues but also meets the growing demand for energy storage solutions. This work investigates the pyrometallurgical reactivation cathode materials of WAB (RC-WABs) at varying pyrolysis temperatures (100, 300, 600, and 1000 °C) to produce high-performance electrode materials for supercapacitors. Among these, cathode materials treated at 600 °C exhibited a highly porous structure with a specific surface area of 78.07 m² g^-1 and a pore volume of 0.983 cm³ g^-1, which significantly enhanced electrochemical performance. The results indicated that this material achieved a specific capacitance of 1177.16 F g^-1 at a current density of 3mA cm^-2 in a 1 M KOH electrolyte and maintained an impressive ≈98% capacitance retention after 10 000 charging cycles. When integrated into a symmetric supercapacitor configuration, these materials demonstrated an energy density of 18.85 Wh kg^-1 and a power density of 224.01 W kg^-1. Hence, the results can provide sustainable solutions for the interconnected challenges of waste management and energy storage.