Bio-Gel Formation Through Enzyme-Induced Carbonate Precipitation for Dust Control in Yellow River Silt

This study explored the enzymatic formation of gel-like polymeric matrices through carbonate precipitation for dust suppression in Yellow River silt. The hydrogel-modified EICP method effectively enhanced the compressive strength and resistance to wind-rain erosion by forming a reinforced bio-cemented crust. The optimal cementation solution, consisting of urea and CaCl₂ at equimolar concentrations of 1.25 mol/L, was applied to improve CaCO₃ precipitation uniformity. A spraying volume of 4 L/m² (first urea-CaCl₂ solution, followed by urease solution) yielded a 14.9 mm thick hybrid gel-CaCO₃ crust with compressive strength exceeding 752 kPa. SEM analysis confirmed the synergistic interaction between CaCO₃ crystals and the gel matrix, where the hydrogel network acted as a nucleation template, enhancing crystal bridging and pore-filling efficiency. XRD analysis further supported the formation of a stable gel-CaCO₃ composite structure, which exhibited superior resistance to wind-rain erosion and mechanical wear. These findings suggest that gel-enhanced EICP represents a novel bio-gel composite technology for sustainable dust mitigation in silt soils.