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Updated: Sep 18, 2025

Preparation of Biomass-based Mesoporous Carbon with Higher Nitrogen-/Oxygen-chelating Adsorption for CuII Through Microwave Pre-Pyrolysis
Published on: February 12, 2019
Efficient Adsorption of Lead on Hydro-Pyrochar Synthesized by Two-Step Conversion of Corn Cob in Magnesium Chloride
Marija Simić1, Jelena Petrović1, Marija Koprivica1
1Institute for Technology of Nuclear and Other Mineral Raw Materials, 11000 Belgrade, Serbia.
Abstract:
This study used widely available waste biomass, corn cob (CC), to remove Pb ions from aqueous solutions. A two-step conversion of this material was carried out to improve its adsorption characteristics. Firstly, CC was prepared by hydrothermal carbonization; afterward, the obtained hydrochar was doped by MgCl2 and pyrolyzed. The synthesized hydro-pyrochar (HCC-Mg) was used for adsorption experiments in a batch system. The surface and structural properties of HCC-Mg were characterized by SEM-EDX and FTIR analysis before and after Pb adsorption. Kinetic and isotherm models were applied to the experimental results. It was confirmed that Pb adsorption on HCC-Mg occurred rapidly, with a maximum adsorption capacity of 87.08 mg/g. The pseudo-second-order model best described the adsorption process, while the best fit of the experimental data was observed with the Sips isotherm model. The results of this study showed that the capacity of the synthesized HCC-Mg material had increased more than 14 times compared with raw CC. In addition, the synthesized material had the potential to be reused for at least five cycles with minimal loss of adsorption capacity and efficiency. Moreover, the results confirmed that HCC-Mg can be used as an efficient, sustainable adsorbent of Pb from polluted water.
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