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Published on: May 15, 2017
Pressure-Induced Structural Phase Transition in Ho2Ce2O7 Oxide
1State Key Laboratory of High Pressure and Superhard Materials, Jilin University, Changchun 130012, China.
Abstract:
The structural evolution of Ho2Ce2O7 under high pressure was systematically investigated using synchrotron X-ray diffraction (up to 31.5 GPa) and Raman spectroscopy (up to 41.7 GPa). At ambient pressure, the compound adopts a common C-type cubic rare earth oxide structure (space group Ia-3). A pressure-induced phase transition was observed to commence at 23.8 GPa, characterized by a gradual structural evolution that persisted through the maximum experimental pressure of 31.5 GPa. This transition involves cation disordering accompanied by coordination environment modifications. High-pressure X-ray diffraction analysis reveals the coexistence of two distinct phases above the transition threshold: the parent cubic phase (Ia-3) and a metastable hexagonal phase (R-3c). Notably, the high-pressure phase configuration persists upon complete decompression to ambient conditions, demonstrating the irreversible nature of this pressure-induced structural transition.
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