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Updated: Sep 17, 2025
Pretreatment of Lignocellulosic Biomass with Low-cost Ionic Liquids
Published on: August 10, 2016
Direct Transformation of Biomass into Levulinic Acid Using Acidic Ionic Liquids: An Example of Sustainable and
Marta Przypis1,2, Agata Wawoczny1,2, Karolina Matuszek3
1Faculty of Chemistry, Department of Organic Chemistry, Bioorganic Chemistry, and Biotechnology, Silesian University of Technology, Krzywoustego 4, 44-100, Gliwice, Poland.
Abstract:
The intensification of the use and conversion of renewable raw materials, including plant biomass, into valuable products is one of the major goals of the Sustainable Development Strategy. Levulinic acid (LA), classified as one of the top twelve biobased platform chemicals of the future, can be produced from lignocellulose; however, this process is often complex. Herein, a novel and effective pathway for the direct transformation of lignocellulosic biomass into LA under mild conditions, without pretreatment, is presented. Selected waste lignocellulosic biomass, including sawmill chips, grass, and walnut waste, as well as model cellulose, is converted to LA using acidic ionic liquids (ILs). Among the evaluated ILs, [Hmim(HSO4)(H2SO4)2] provided the highest product yields even at 50-70 °C. The ILs used herein are significantly more efficient in converting cellulose and biomass compared to conventional sulfuric acid. The highest yield of LA is obtained from sawmill chips, reaching 64.04 mol% of LA.
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