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Facile Preparation of Internally Self-assembled Lipid Particles Stabilized by Carbon Nanotubes
Published on: February 19, 2016
Research on Enhanced Oil Recovery and In Situ Drag Reduction Mechanism of Janus Amphiphilic Carbon Nanotube
Qingyuan Chen1,2,3,4, Maofan Ye1, Tianyu Liu4
1State Key Lab Oil & Gas Reservoir Geol & Exploitat, Southwest Petr Univ, Chengdu 610500 Sichuan, Peoples R China.
Abstract:
Heavy oil reservoirs possess abundant reserves but currently exhibit low recovery efficiency, indicating significant untapped exploitation potential. This study developed a Janus amphiphilic carbon nanotube (JCMS18) nanoviscosity-reduction system (JC-F) by formulating laboratory-synthesized JCMS18 with cocamidopropyl betaine and sodium alcohol ether sulfate. Compared with existing nanofluid systems, the developed JC-F demonstrates superior performance at an ultralow concentration (0.12 wt %), achieving a viscosity reduction exceeding 99% and an EOR efficiency of over 20%. The oil-water-rock interaction mechanisms of JC-F were systematically investigated through interfacial activity experiments, emulsification performance evaluation, wettability alteration tests, static adsorption experiments, and molecular dynamics simulations. Results demonstrate that JCMS18 forms stable oil-in-water (O/W) emulsions (2-5 μm droplets) with 99% viscosity reduction and converts oil-wet surfaces to neutral-wet. Capillary pressure reduction experiments, axial pressure distribution measurements, and core flooding tests revealed 30% capillary pressure reduction (30 μm hydrophilic capillaries), 21.32%-24.76% enhanced oil recovery (523-1517 mD cores), and 40%-51.8% drag reduction. Synchronized midsection/injection-end pressure trends in sandpack tube experiments confirmed stable porous media migration. Oil film stripping experiments and microscopic flooding experiments identified synergistic mechanisms: emulsification-induced viscosity reduction, wettability alteration, and wedge-type pressure-driven oil stripping, improving displacement efficiency and sweep volume. These findings provide theoretical guidance for efficient heavy oil recovery.

