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Nitroarene Photoactivation Promotes Oxidative Deconstruction of Olefinic Polymers

Thi H Le1, Kamal Bhatt2, Sylwia Dworakowska1,3

  • 1George & Josephine Butler Polymer Research Laboratory, Center of Macromolecular Science & Engineering, Department of Chemistry, University of Florida, Gainesville, Florida 32611, United States.

ACS Macro Letters
|July 1, 2025
PubMed
Summary

This study demonstrates that photoexcited nitroarenes can efficiently degrade olefinic polymers via oxidative cleavage under visible light. This offers a safe, sustainable, and mild method for macromolecular deconstruction.

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