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Updated: Sep 17, 2025

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Large-Area Monocrystalline Copper Microflake Synthesis.

Elif Nur Dayi1, Diotime Pellet1, Priscila Vensaus1

  • 1Laboratory of Nanoscience for Energy Technologies (LNET), STI, École Polytechnique Fédérale de Lausanne, 1015 Lausanne, Switzerland.

The Journal of Physical Chemistry. C, Nanomaterials and Interfaces
|July 2, 2025
PubMed
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Researchers developed a novel wet synthesis method for large, stable copper microflakes. This technique avoids byproducts and offers enhanced oxidation resistance for catalysis and nanophotonics applications.

Area of Science:

  • Materials Science
  • Nanotechnology
  • Surface Chemistry

Background:

  • Copper (Cu) is crucial for energy conversion, catalysis, and nanophotonics.
  • Current synthesis methods for Cu materials suffer from byproducts and poor morphology control.

Purpose of the Study:

  • To develop a facile on-substrate wet synthesis for high-quality copper microflakes.
  • To achieve large sizes, high aspect ratios, and enhanced stability in synthesized Cu.

Main Methods:

  • On-substrate wet synthesis technique.
  • Systematic study of the copper growth mechanism.
  • Characterization of microflake morphology, crystallinity, and stability.

Main Results:

  • Produced purely metallic, monocrystalline Cu microflakes with exposed (111) surfaces.

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  • Achieved unprecedented microflake sizes >130 μm and aspect ratios >400.
  • Demonstrated enhanced oxidation stability due to a halide adlayer, eliminating surfactant use.
  • Conclusions:

    • The facile synthesis method yields high-quality, large-scale copper microflakes.
    • The resulting microflakes offer superior stability and morphology for advanced applications.
    • This approach opens new possibilities in catalysis and nanophotonics.