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Improving municipal solid waste co-composting performance using activated biochar, leonardite, and MgSO4-modified
Kamal Khalkhal1, Adel Reyhanitabar2, Shahin Oustan2
1Department of Soil Science, Faculty of Agriculture, University of Tabriz, Tabriz, Iran. k.khalkhal@tabrizu.ac.ir.
Environmental Monitoring and Assessment
|July 2, 2025
Summary
Acid and base-activated biochars significantly enhance municipal solid waste (MSW) co-composting. NaOH-activated biochar (NaOH-AB) improved maturity and nutrient content, while H2SO4-activated biochar (H2SO4-AB) boosted organic matter and reduced heavy metals.
Area of Science:
- Environmental Science
- Soil Science
- Waste Management
Background:
- Municipal solid waste (MSW) co-composting requires effective amendments to improve compost quality.
- Biochar, zeolite, and leonardite are potential additives for waste stabilization and nutrient enrichment.
Purpose of the Study:
- To evaluate the impact of H2SO4-activated biochar (H2SO4-AB), NaOH-activated biochar (NaOH-AB), MgSO4-modified zeolite, and leonardite on MSW co-composting.
- To determine the effects of these additives on compost maturity, stability, and quality parameters.
Main Methods:
- Co-composting of MSW with various additives: H2SO4-activated biochar, NaOH-activated biochar, MgSO4-modified zeolite, and leonardite.
- Monitoring of key maturity and stability parameters throughout the co-composting period.
- Analysis of microbial respiration, dehydrogenase activity, humification, nutrient content, and heavy metal concentrations.
Main Results:
- NaOH-AB and H2SO4-AB modified biochar surfaces, enhancing microbial activity and respiration rates by an average of 24% compared to control.
- Leonardite amendment led to higher humification, while 5% NaOH-AB compost showed the longest thermophilic phase (7 days), highest temperature (71.5°C), germination index (130.9%), and total nitrogen (1.37%).
- 10% H2SO4-AB compost exhibited maximum organic matter (36.8%), C/N ratio (18.1), lowest nitrate, and reduced heavy metal availability (Zn, Fe, Mn, Pb).
Conclusions:
- Acid and base-activated biochars are effective additives for improving MSW co-compost quality.
- NaOH-AB and H2SO4-AB treatments offer distinct advantages in terms of maturity, nutrient content, organic matter, and pollutant reduction.
- These activated biochars represent promising solutions for sustainable MSW management and compost production.

