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Updated: Sep 16, 2025
Hyperspectral Imaging as a Tool to Study Optical Anisotropy in Lanthanide-Based Molecular Single Crystals
Published on: April 14, 2020
Dual-Sided Multidentate Coordination Strategy Enables Record Birefringence in UV-Transparent Antimony-Based Hybrid
Pu Zhang1,2, Xuehua Dong1, Ling Huang1
1College of Chemistry and Materials Science, Sichuan Normal University, Chengdu, 610066, P.R. China.
Abstract:
Achieving ultrahigh birefringence in UV-transparent materials remains fundamentally constrained by the trade-off between strong optical anisotropy and wide bandgap transparency. Herein, we report a dual-sided multidentate coordination (DMC) strategy to construct two butterfly-shaped UV organic-inorganic hybrid crystals-(C6H4NO2)2SbF (PCSF) and (C10H6NO2)2SbF (QCSF)-in which planar π-conjugated bidentate ligands symmetrically chelate stereochemically active lone pair (SCALP) Sb3+ centers. This coordination architecture enforces coplanar alignment of optical functional units and promotes dense π-π stacking, thereby significantly enhancing macroscopic birefringence. Notably, QCSF achieves a record-high birefringence of Δn = 0.87 at 546 nm, surpassing all previously reported lone-pair-containing halide crystals with UV transparency. The exceptional optical performance is attributed to the unique [SbN2O2F] coordination geometry, near-planar molecular configuration, and extended π-electron delocalization. First-principles calculations reveal that the observed anisotropy stems from synergistic orbital coupling between the Sb centers and the π-conjugated organic ligands. This work introduces a broadly applicable molecular design paradigm for next-generation birefringent crystals that simultaneously offer high optical anisotropy and UV transparency.
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