Experimental Evaluation and Thermodynamic Analysis of Magnetic Fe₃O₄@La-Zr-MOFs for Highly Efficient Fluoride and...

Phosphate and fluoride ions are common water pollutants whose presence and excessive discharge cause potential hazards to the environment and human health. MOF materials commonly used to remove phosphate and fluoride ions are usually in powder form, with low recovery during regeneration. Herein, to address these issues, Fe₃O₄@La-Zr-MOFs magnetic composites for phosphate and fluoride removal were fabricated by means of the hydrothermal method. The adsorption properties of the adsorbent were systematically assessed by means of adsorption experiments. The magnetic Fe₃O₄@La-Zr-MOFs exhibited a magnetic recovery efficiency of 93%, and they could maintain outstanding adsorption performance at a broad range of pH values and superior selectivity for phosphate and fluoride ions. The adsorption process conformed to the Langmuir isotherm and pseudo-second-order models, indicating that it was dominated by monomolecular chemisorption. Further characterization of the Fe₃O₄@La-Zr-MOFs before and after adsorption and kinetic thermodynamic investigation revealed that the elimination mechanism of phosphate and fluoride ions by Fe₃O₄@La-Zr-MOFs includes ion exchange, electrostatic interactions, and surface complexation. This study demonstrates that magnetic reusable Fe₃O₄@La-Zr-MOFs composites have great promise for phosphate and fluoride removal and recovery.