All-Day Freshwater Harvesting Using Solar Auto-Tracking Assisted Selective Solar Absorption and Radiative Cooling

The shortage of freshwater resources has become the core bottleneck of global sustainable development. Traditional freshwater harvesting technologies are restricted by geographical conditions and environmental limitations, making them increasingly difficult to satisfy the growing water demand. In this study, based on the synergistic coupling mechanism of photothermal conversion and radiative cooling, a solar auto-tracking assisted selective solar absorber and radiative cooling all-weather freshwater harvesting device was innovatively developed. The prepared selective solar absorber achieved a high absorptivity of 0.91 in the solar spectrum (0.3-2.5 μm) and maintained a low emissivity of 0.12 in the mid-infrared range (2.5-20 μm), significantly enhancing the photothermal conversion efficiency. The radiative cooling film demonstrated an average cooling effect of 7.62 °C during typical daytime hours (12:00-13:00) and 7.03 °C at night (22:00-23:00), providing a stable low-temperature environment for water vapor condensation. The experimental results showed that the experimental group equipped with the solar auto-tracking system collected 0.79 kg m^-2 of freshwater in 24 h, representing a 23.4% increase compared to the control group without the solar auto-tracking system. By combining theoretical analysis with experimental validation, this study presents technical and economic advantages for emergency water and island freshwater supply, offering an innovative solution to mitigate the global freshwater crisis.