Enhanced Thermal Conductivity of Polytetrafluoroethylene Dielectric Composite with Fluorinated Graphite Inducing...

Polytetrafluoroethylene (PTFE) has been widely used as a high-frequency dielectric substrate due to its excellent dielectric properties and thermal stability. However, with its low intrinsic thermal conductivity, PTFE falls short in meeting the escalating heat dissipation demands of high-power density, high-frequency communication systems. Although the thermal conductivity of PTFE composites can be effectively improved by the high thermal conductivity fillers, it is always accompanied by a decline in dielectric properties. Molecular chain ordering is regarded as an effective strategy to improve the intrinsic thermal conductivity of polymers while maintaining dielectric properties. Unfortunately, the conventional preparation methods for ordered molecular chains, such as electrostatic spinning and uniaxial stretching, are not applicable to the preparation of PTFE substrates. In this work, fluorinated graphite (FGi) is employed to induce the in-plane orientation of PTFE molecular chains. As a result, the PTFE composite with 0.5 wt% FGi loading exhibits an in-plane thermal conductivity of 1.21 W·m^-1·K^-1, six times higher than the in-plane thermal conductivity of pure PTFE. In addition, this composite exhibits a superior dielectric constant of 2.06 and dielectric loss of 0.0021 at 40 GHz. This work introduces a facile method to achieve improved thermal conductivity of PTFE while maintaining its excellent dielectric properties.