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Updated: May 3, 2026
Preparation of Highly Porous Coordination Polymer Coatings on Macroporous Polymer Monoliths for Enhanced Enrichment of Phosphopeptides
Published on: July 14, 2015
Permanently porous oligoMOFs and polyMOFs of MIL-53
Debobroto Sensharma1, Seth M Cohen1
1Department of Chemistry and Biochemistry, University of California San Diego, La Jolla, California 92093, USA. scohen@ucsd.edu.
Abstract:
Enhancing the porosity of metal-organic frameworks (MOFs) typically relies on substituting their organic ligand components. Here, we show that cross-linked terephthalate ligands yield oligoMOF and polyMOF versions of MIL-53(In) in which pressure-dependent phase transformations no longer occur. These materials show enhanced uptakes and CO2/N2 selectivity, while retaining the overall MIL-53 framework.
