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Open-Shell Pd(II) and Ni(II) Complexes Supported by Cyclic(alkyl)(amino)carbene-Derived Carbon Disulfide Radical

Gayeong Lim1,2, Dongmin Kang1,2, Jeongcheol Shin3

  • 1Department of Chemistry, Pusan National University, Busan 46241, Republic of Korea.

ACS Omega
|July 21, 2025
PubMed
Summary

Cyclic-(alkyl)-(amino)-carbene derived carbon disulfide adducts act as radical ligands. These ligands stabilize palladium and nickel complexes with multiconfigurational electronic structures, showing potential for catalysis.

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