Biomacromolecular engineering of redox-active chitosan-polypyrrole-clay hybrid materials for machine...

The bentonite chitosan polypyrrole (Bent-CS-PPy) composite was engineered as a multifunctional material with dual capabilities: the efficient adsorption of dibenzothiophene (DBT) from model fuel and application as an electrode in electrochemical energy storage systems. This hybrid composite leverages the layered morphology and cation-exchange capacity of bentonite, the hydrophilic and functional -OH and -NH₂ groups of chitosan, and the redox-active, π-conjugated polymeric framework of polypyrrole, resulting in a porous, conductive, and chemically interactive matrix. In adsorptive desulfurization studies, the Bent-CS-PPy composite exhibited a DBT removal efficiency of 81.26 % under optimized conditions. The adsorption kinetics followed a pseudo-second-order model and fit the Langmuir isotherm, with a monolayer adsorption capacity of 33.71 mg/g. Machine learning (ML) algorithms including nonlinear regression (NLR), artificial neural networks (ANN), and support vector regression (SVR) were employed to predict DBT removal performance, with the ANN model demonstrating the highest predictive accuracy. Furthermore, the composite was evaluated as a symmetric supercapacitor electrode, delivering an energy density of 44.67 Wh/kg and a power density of 500 W/kg. Notably, it retained 73.44 % of its initial capacitance after 13,000 continuous charge-discharge cycles. These results underscore the potential of Bent-CS-PPy as a sustainable, dual-functional material for integrated environmental remediation and energy storage applications.