Enhancing s-CO₂ Brayton Power Cycle Efficiency in Cold Ambient Conditions Through Working Fluid Blends

Supercritical carbon dioxide (s-CO₂) Brayton cycles have emerged as a promising technology for high-efficiency power generation, owing to their compact architecture and favorable thermophysical properties. However, their performance degrades significantly under cold-climate conditions-such as those encountered in Greenland, Russia, Canada, Scandinavia, and Alaska-due to the proximity to the fluid's critical point. This study investigates the behavior of the recompression Brayton cycle (RBC) under subzero ambient temperatures through the incorporation of low-critical-temperature additives to create CO₂-based binary mixtures. The working fluids examined include methane (CH₄), tetrafluoromethane (CF₄), nitrogen trifluoride (NF₃), and krypton (Kr). Simulation results show that CH₄- and CF₄-rich mixtures can achieve thermal efficiency improvements of up to 10 percentage points over pure CO₂. NF₃-containing blends yield solid performance in moderately cold environments, while Kr-based mixtures provide modest but consistent efficiency gains. At low compressor inlet temperatures, the high-temperature recuperator (HTR) becomes the dominant performance-limiting component. Optimal distribution of recuperator conductance (UA) favors increased HTR sizing when mixtures are employed, ensuring effective heat recovery across larger temperature differentials. The study concludes with a comparative exergy analysis between pure CO₂ and mixture-based cycles in RBC architecture. The findings highlight the potential of custom-tailored working fluids to enhance thermodynamic performance and operational stability of s-CO₂ power systems under cold-climate conditions.