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Mechanical Properties of Fully Recyclable 3D-Printable Materials Used for Application in Patient-Specific Devices in
Antonio Jreije1, Paulius Griškevičius2, Neringa Keršienė2
1Department of Physics, Kaunas University of Technology, Studentu Str. 50, 51368 Kaunas, Lithuania.
Polymers
|July 30, 2025
Summary
3D-printed ABS with bismuth oxide (Bi2O3) shows promise for sustainable medical devices. This recyclable composite maintains mechanical strength after multiple recycling and irradiation cycles, ideal for radiotherapy applications.
Area of Science:
- Materials Science
- Biomedical Engineering
- Additive Manufacturing
Background:
- Healthcare plastics pose environmental challenges due to production growth and recycling limitations.
- 3D printing offers localized, on-demand manufacturing solutions for the medical sector.
- Reusable medical devices are needed to improve sustainability in healthcare.
Purpose of the Study:
- To evaluate the mechanical properties and recyclability of 3D-printed ABS composites with Bi2O3 fillers.
- To assess the material's suitability for reusable radiotherapy support devices after recycling and irradiation.
- To determine the optimal Bi2O3 concentration for enhanced material performance.
Main Methods:
- Filaments of PLA, ABS, and ABS composites (5 wt% and 10 wt% Bi2O3) were extruded.
- Materials underwent up to ten recycling cycles (shredding and re-extrusion).
- Samples were irradiated to 70 Gy using a 6 MeV photon beam to simulate radiotherapy conditions.
Main Results:
- ABS showed better recyclability than PLA, but experienced a decline in tensile strength and Young's modulus after ten cycles.
- ABS with 5 wt% Bi2O3 demonstrated significantly improved recyclability and mechanical property retention.
- The ABS-5 wt% Bi2O3 composite maintained superior mechanical integrity after irradiation, with minimal degradation.
Conclusions:
- ABS-5 wt% Bi2O3 is a promising recyclable material for durable, patient-specific radiotherapy devices.
- This composite supports sustainability in medical manufacturing by enabling the creation of robust, reusable components.
- The findings highlight the potential of additive manufacturing and composite materials to address environmental challenges in healthcare.

