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Ultra-compact, low-loss silicon photonic phase shifter enabled by a ferroionic two-dimensional material
Optics Express
|July 30, 2025
Summary
We demonstrate a new tunable optical material, copper chromium phosphorus sulfide (CuCrP2S6), for silicon photonics. This 2D material enables efficient, low-loss phase modulation in the short-wave infrared, crucial for advanced photonic integrated circuits.
Area of Science:
- Materials Science
- Optoelectronics
- Nanotechnology
Background:
- Tunable optical materials are critical for electro-optic functions in photonic integrated circuits (PICs).
- Two-dimensional (2D) materials provide strong light-matter interactions, ideal for compact tunable devices.
- Achieving efficient, low-loss broadband phase modulation in the short-wave infrared (SWIR) is a persistent challenge.
Purpose of the Study:
- To demonstrate electro-refractive tuning in silicon photonic imbalanced Mach-Zehnder interferometers (UMZIs).
- To investigate the use of multilayer CuCrP2S6 (CCPS), a ferroionic 2D material, for phase modulation.
- To assess the performance of CCPS-based phase shifters in terms of efficiency, loss, and voltage-length product.
Main Methods:
- Hybrid integration of multilayer CCPS with silicon photonic UMZIs.
- Modulation driven by reversible copper ion migration at the metal-semiconductor interface.
- Characterization of refractive index change and phase shift across devices.
Main Results:
- Achieved a significant refractive index change of 1.5 × 10^-2 refractive index units (RIU).
- Observed a consistent redshift of 7.0-7.4 nm at 8 V, corresponding to a 0.8π phase shift.
- Demonstrated a low half-wave voltage-length product (Vπ·L) of 0.033 V·cm with negligible optical loss at 1.55 µm.
Conclusions:
- CuCrP2S6 (CCPS) exhibits excellent electro-refractive tuning capabilities for silicon photonics.
- CCPS outperforms existing transition metal dichalcogenides (TMDs) in phase shifter performance.
- These findings highlight CCPS as a promising material for high-efficiency, ultra-compact phase shifters in SWIR applications.

