Related Experiment Video
Updated: Sep 13, 2025

Excitonic Hamiltonians for Calculating Optical Absorption Spectra and Optoelectronic Properties of Molecular Aggregates and Solids
Published on: May 27, 2020
Permutation entropy for the characterization of the attractive Hamiltonian mean-field model
Melissa G Fuentealba1, Danilo M Rivera1, Roberto E Navarro1
1Universidad de Concepción, Departamento de Física, Facultad de Ciencias Físicas y Matemáticas, Concepción 4070386, Chile.
Abstract:
The Hamiltonian mean-field (HMF) model is a long-range interaction system that exhibits quasistationary states (QSS), which persist for long times before reaching thermodynamic equilibrium. These states are traditionally characterized by homogeneous/demagnetized or nonhomogeneous/magnetized phase-space structures, separated by an out-of-equilibrium phase transition that depends on the initial energy u_{0} and magnetization M_{0} of the system. However, the magnetization also exhibits fluctuations around its mean value in time, which can provide additional insights into the nature of the QSS. In this study, the permutation entropy H and the statistical complexity C are used as tools to characterize the dynamical properties of these magnetization fluctuations. It is found that most data points lie above the entropy-complexity curve for stochastic processes with a power-law spectrum (k noise), suggesting that the magnetization retains more structure than purely stochastic processes. As the initial energy u_{0} increases, both H and C exhibit global minima that align closely with the critical energy u^{*} separating magnetized and demagnetized QSSs. This agreement is particularly strong for M_{0}≲0.4, where a first-order out-of-equilibrium phase transition has been reported for the HMF model. Below this transition, magnetized QSSs are associated with more ordered fluctuations, exhibiting fewer correlated structures. Above this transition, demagnetized QSSs are characterized by fluctuations that shift toward more complex and more disordered dynamics, with an increasing number of correlated structures as u_{0} increases.
Related Concept Videos
Entropy
Atomic Nuclei: Nuclear Spin State Population Distribution
Entropy Change in Reversible Processes
The statement can be further generalized to prove that entropy is a state function. Take a cyclic process between any two points on a p-V diagram.
The Quantum-Mechanical Model of an Atom
Paramagnetism
Standard Entropy Change for a Reaction

