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Molecular Models02:00

Molecular Models

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Related Experiment Video

Updated: Jul 3, 2026

Preparation of Graphene Liquid Cells for the Observation of Lithium-ion Battery Material
10:53

Preparation of Graphene Liquid Cells for the Observation of Lithium-ion Battery Material

Published on: February 5, 2019

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Macroscopic Graphene Oxide Hollow Spheres.

Bo Wang1, Yiwen Chen1, Gabriele Capilli1

  • 1Department of Mining and Materials Engineering, McGill University, Montreal, QC H3A 0C5, Canada.

Nano Letters
|August 1, 2025
PubMed
Summary

Researchers created ultralight graphene oxide (GO) hollow spheres inspired by soap bubbles. These self-assembled GO spheres exhibit remarkable size ratios and can encapsulate particles, showing potential for diverse applications.

Keywords:
diameter-to-wall thickness ratiogas barriergraphene oxidehollow spheresoap bubble

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Area of Science:

  • Materials Science
  • Nanotechnology
  • Chemical Engineering

Background:

  • Graphene oxide (GO) is a 2D material with unique properties.
  • Hollow structures offer advantages in various applications.
  • Controlling self-assembly of nanomaterials is crucial for advanced materials.

Purpose of the Study:

  • To develop a method for creating millimeter-sized graphene oxide (GO) hollow spheres.
  • To investigate the self-assembly properties of GO in bubble formation.
  • To explore the potential applications of these GO hollow spheres.

Main Methods:

  • Producing GO-stabilized bubbles by blowing air into a GO and surfactant suspension.
  • Air-drying the bubbles to form self-supporting hollow spheres.
  • Encapsulating particles within the bubbles in a hydrated state.
  • Thermal treatment to form reduced GO (rGO) hollow spheres.
  • Coating rGO spheres with poly(ethylenimine)/GO shells.

Main Results:

  • Achieved self-supporting hollow spheres with an exceptional diameter-to-wall thickness ratio (65,000).
  • Obtained ultralow density spheres (0.16 mg/cm³).
  • Demonstrated GO self-assembly into nanometer-thin lamellar walls preventing bubble collapse.
  • Showcased particle encapsulation within hollow spheres.
  • Developed rGO hollow spheres with gas transport inhibiting shells.

Conclusions:

  • Millimeter-sized GO hollow spheres can be fabricated using a bubble-blowing method.
  • The self-assembly of GO during drying leads to stable, ultralight structures.
  • These GO and rGO hollow spheres have significant potential for applications due to their unique properties and tunability.